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Stereoselective Total Synthesis of (-)-Anamarine from D-Mannitol

Karnekanti Rajender, Venkateshwarlu R, Venkateswara Rao P

Stereoselective total synthesis of (-)-anamarine was achieved from D-mannitol through demonstrating the effect of electron withdrawing group in cross-metathesis reaction. The key reactions involved are regioselective ring opening, cross-metathesis and ring closing metathesis reactions.